Quantitative Chemistry (chemistry only)

Percentage Yield

Even though no atoms are gained or lost in a chemical reaction, it is not always possible to obtain the calculated amount of a product because:

  • the reaction may not go to completion because it is reversible
  • some of the product may be lost when it is separated from thereaction mixture
  • some of the reactants may react in ways different to the expectedreaction

The amount of a product obtained is known as the yield. When compared with the maximum theoretical amount as a percentage, it is called the percentage yield.

We can work out a % of what we have made, compared to what we expected:

% yield = (actual yield ÷ theoretical yield) x 100

If a reaction should produce 50 g of product, but only produces 42 g, then we can use the above equation to calculate that the percentage yield is 84% ((42 ÷ 50) x 100)

Percentage Yield

Atom Economy

The atom economy (atom utilisation) is a measure of the amount of starting materials that end up as useful products. It is important for sustainable development and for economic reasons to use reactions with high atom economy.

The percentage atom economy of a reaction is calculated using the balanced equation for the reaction as follows:

% atom economy = (RFM of product ÷ RFM of all reactants) x 100

If we have a high atom economy, then the majority of the atoms we put into the equation are what we get out!

A reaction that only produces one product, will have a 100% atom economy.

Atom Economy

Reaction Pathways

Higher Tier

Usually, there is more than one way to make a particular chemical. A reaction pathway describes the sequence of reactions needed to produce the desired product.

The pathway chosen for a product depends on factors such as:

  • percentage yield
  • atom economy
  • rate of reaction
  • equilibrium position
  • usefulness of by-products

Reaction Pathways: Making Ethanol

Concentration

solution is formed when a solute dissolves in a solvent. The concentration of a solution is a measure of the mass, or amount of solute, dissolved in a given volume of solvent. The more concentrated the solution, the more particles it contains in a given volume.

Higher Tier

The concentration of a solution can be calculated using:

  • the moles of dissolved solute (in mol)
  • the volume of solvent (in dm3)

concentration = moles of solute  ÷ volume of solvent

The units for concentration are mol/dm3, but they may also be written as moldm-3 - don't worry as these mean the same thing.

Converting from grams to moles

You need to be able to calculate concentration in gdm-3 and be able to convert these units into mol/dm3.

To do this, think back to our moles equations, where:

 moles = mass ÷ Mr

For example, a solution of sodium hydroxide has the concentration of 5 g/dm3.
To convert it into mol/dm3, we divide 5 ("the mass") by 40 (the Mr of NaOH).
This gives a concentration of 0.125 mol/dm3.

Concentration Calculations

Volume unit conversions

  • divide by 1000 to convert from cm3 to dm3
  • multiply by 1000 to convert from dm3 to cm3

Titration Calculations

Higher Tier

Knowing the concentration of a solution and the volume we can work out the number of moles in a solution using the equation:

concentration = moles of solute  ÷ volume of solvent

Worked Example

NaOH + HCl → NaCl + H2O

During a titration, 25 ml of sodium hydroxide was used to neutralise hydrochloric acid. This is the same as 0.025 dm3.
If the concentration of the alkali is 0.12 mol/dm3, then the amount of moles used is 0.025 x 0.12 = 0.003 moles.

NaOH HCl
concentration 0.12 ?
volume 0.025 ?
moles 0.003 ?

If hydrochloric acid (unknown concentration) completely neutralises the alkali then we know that 0.003 moles of acid were also present (because the balanced symbol equation shows a 1:1 ratio of acid reacting with alkali).
If 26.8 ml of acid were needed to neutralise 25 ml of alkali, we know 0.0268 dm3 acid were used.

NaOH HCl
concentration 0.12 ?
volume 0.025 0.0268
moles 0.003 0.003

The concentration of the acid then uses the above equation again (but rearranged):

concentration = moles ÷ volume

So the concentration of the acid used = 0.003 ÷ 0.0268 = 0.11 mol/dm3

Titration Equipment

Calculating average titres

When completing a titration, you will have multiple readings which you need to calculate an average reading for.

It is important that the titres you include in your calculation are concordant. If they are not, you will lose marks in an exam.

Below are some results from a titration experiment.

rough run 1 run 2 run 3
final reading 15.05 14.70 14.75 14.70
initial reading 0.05 0.05 0.00 0.00
titre (ml) 15.00 14.65 14.75 14.70

The average titre for these results would only include the values from run 1, 2 and 3 as these are the only concordant results.

Avagadro's Law

Higher Tier

Avogadro's law states that equal volumes of different gases contain an equal number of molecules (this only applies at room temperature and pressure, 20°C and 1 atmosphere pressure).

The molar volume is the volume occupied by one mole of molecules of any gas at room temperature and pressure.
The molar volume is 24 dm3 or 24000 cm3.

Avogadro's law can be used to calculate the volumes of gases involved in reactions:

hydrogen reacts with chlorine to form hydrogen chloride
H2(g) + Cl2(g) → 2HCl(g)

The mole ratio of hydrogen to chlorine is 1:1, and of reactants to products is 1:2. This means, for example:

  • 1 cm3 of hydrogen reacts exactly with 1 cm3 of chlorine, and will make 2 cm3 of hydrogen chloride
  • 250 cm3 of hydrogen reacts exactly with 250 cm3 of chlorine, and will make 500 cm3 of hydrogen chloride
  • 1 dm3 of hydrogen reacts exactly with 1 dm3 of chlorine, and will make 2 dm3 of hydrogen chloride

Calculations with Gases

Higher Tier

2Na(s) + 2H2O(l) → 2NaOH(aq) + H2(g)

5.0 g of sodium reacts fully with water. Calculate the volume of hydrogen produced.
(Ar of Na = 23, molar volume = 24 dm3)

Na H2
mass/volume 5.0 g ?
Mr 23 x
moles 0.217 ?

If sodium completely reacts with water, then we know that 0.217 moles of sodium will make 0.109 moles of hydrogen (because the balanced symbol equation shows a 2:1 ratio of sodium reacting to make hydrogen).

Na H2
mass/volume 5.0 g ?
Mr 23 x
moles 0.217 0.109

1 mole of gas takes up a volume of 24 dm3

So the volume of hydrogen produced = 0.109 x 24 = 2.61 dm3

Molar Gas Calculatations